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Sei, a 20-year-old office worker, is whisked away to a whole new world. Unfortunately for Sei, the ritual that summoned her—meant to produce a "Saint" who would banish the dark magic—brought two people over instead of one. And everyone prefers the second girl over Sei?! But this is just fine by Sei, who leaves the royal palace to set up shop making potions and cosmetics with her newfound magic. Business is booming, and this might not be such a bad life, after all...as long as her supposed Sainthood doesn't come back to haunt her.

Awakening her dormant abilities as a devil one day, Yuuko Yoshida aka Shadow Mistress Yuuko, is entrusted with the mission to defeat the Light clan's shrine maiden, a magical girl, by her ancestor Lilith. Yuuko meets magical girl Momo Chiyoda through her classmate Anri Sada, and challenges her to a duel, but loses quickly due to her lack of strength. Since then, Yuuko has struggled with her role as a devil and her duel with Momo, and borrowed help from her regularly. However, by a strange coincidence, Yuuko also weakens Momo by taking away her power to cooperate in protecting the peace of Tama city.

Weighed down by memories she can't shake, high schooler Koyuki Hikawa keeps everyone at arm's length — until three schoolmates draw her out of her shell.

Takemichi Hanagaki is a freelancer that’s reached the absolute pits of despair in his life. He finds out that the only girlfriend he ever had, in middle school, Hinata Tachibana, had been killed by the ruthless Tokyo Manji Gang. The day after hearing about her death, he’s standing on the station platform and ends up being pushed over onto the tracks by a herd of people. He closes his eyes thinking he’s about to die, but when he opens his eyes back up, he somehow had gone back in time 12 years. Now that he’s back living the best days of his life, Takemichi decides to get revenge on his life.